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Antacids (P. Chemistry | Ch-3 | Unit-2): Latest D Pharma 1st year Notes

What are Antacids?

Antacids are substances that neutralise gastric pH by binding to or inhibiting gastric receptors. They inhibit excess hydrochloric acid secretion in the stomach and neutralise rising HCl levels.

Hydrochloric acid (HCl) with a pH of about 1.5–2.5 helps digestion by activating gastric enzymes. When its concentration increases it causes indigestion, heartburn, gastric upset, and gastrointestinal ulcers. Most antacids act on H₂ receptors or the proton pump inhibitor (PPI) pathway to maintain H⁺ ion concentration.

Classification of Antacids

By acting site:

TypeExamples
H₂ Receptor AntagonistsCimetidine, Ranitidine, Famotidine
Proton Pump InhibitorsEsomeprazole, Omeprazole, Pantoprazole

By inorganic elemental nature:

TypeExamples
Calcium containingCalcium carbonate, Tribasic calcium phosphate
Magnesium containingMagnesium hydroxide, Magnesium carbonate, Magnesium oxide, Magnesium trisilicate
Aluminium containingAluminium hydroxide, Aluminium phosphate, Aluminium carbonate
Sodium containingSodium bicarbonate
Combined antacidsAl(OH)₃ + Mg(OH)₂; Al(OH)₃ + Magnesium trisilicate; Al(OH)₃ + Calcium carbonate

Note: Calcium and aluminium antacids may cause constipation. Magnesium antacids may cause laxative effects.


Aluminium Hydroxide Gel

  • Formula: Al(OH)₃
  • Molar Mass: 78.00 g/mol
  • Also known as: Aluminic acid, Hydrated Alumina
PropertyDescription
Color & StateWhite or pale yellow amorphous powder
Odour & TasteOdourless; mucilaginous taste
SolubilityInsoluble in water; soluble in acidic and basic medium
  • Preparation: Suspension, syrup, tablet, capsule, bolus.
  • Brand names: Digene, Gelusil, Vicid, Alqure, Asinil-T.
  • Storage: Well-closed, airtight container; away from light and moisture

Uses:

  • Treats gastric problems by neutralising excess HCl
  • Relieves heartburn, upset stomach, and sour stomach
  • Reduces phosphate levels in patients with kidney conditions

Magnesium Hydroxide

  • Formula: Mg(OH)₂
  • Molar Mass: 58.32 g/mol
  • Also known as: Milk of Magnesia

Preparation (commercial): Mg²⁺ + Ca(OH)₂ → Mg(OH)₂ + Ca²⁺

PropertyDescription
Color & StateWhite crystalline solid or powder
Odour & TasteOdourless; milky or chalky taste
SolubilitySlightly soluble in water
  • Preparation: Suspension, syrup, tablet, capsule.
  • Brand names: Digene, Gelusil, Antanil Plus, Cremaffin, Maalox.
  • Storage: Well-closed, airtight container; away from light and moisture

Uses:

  • Reduces stomach acid; increases water in intestines to induce bowel movements
  • Used as a laxative to relieve constipation
  • Relieves indigestion, sour stomach, and heartburn

Magaldrate

  • Formula: Al(OH)₃·Mg₂(OH)₄·H₂O
  • Molar Mass: 212.67 g/mol
  • Also known as: Magnesium Aluminium Monohydrate
  • First synthesised by: German chemist Gunther Hallmann
PropertyDescription
Color & StateWhite crystalline powder or paste
Odour & TasteOdourless; milky taste
SolubilityPractically insoluble in water and ethanol; soluble in mineral acids
  • Preparation: Syrup, suspension, tablet, powder
  • Brand names: Gasorit, Novelta, Metadrate, Pracid, Contacid
  • Storage: Well-closed, airtight container; away from light and moisture

Uses:

  • Treatment of duodenal and gastric ulcers
  • Treatment of oesophagitis from gastroesophageal reflux disease (GERD)
  • Also used in hyperphosphataemia

Sodium Bicarbonate

  • Formula: NaHCO₃
  • Molar Mass: 84.01 g/mol
  • Commonly known as: Baking soda

Industrial preparation: NaCl + NH₃ + CO₂ + H₂O → NaHCO₃ + NH₄Cl

PropertyDescription
Color & StateWhite crystalline powder
Odour & TasteOdourless; saline taste
SolubilityHighly soluble in water; practically insoluble in alcohol
  • Preparation: Tablets, powder, ear drops, injection, capsule, sachet, syrup, suspension.
  • Brand names: Nodosis, Gaviscon, Alka Soda, Rencarb, Sodamint.
  • Storage: Well-closed, airtight container; away from light and moisture

Uses:

  • Treatment of metabolic acidosis in severe renal disease, uncontrolled diabetes, circulatory insufficiency
  • Relieves heartburn, sour stomach, and acid indigestion by neutralising excess stomach acid

Calcium Carbonate

  • Formula: CaCO₃
  • Molar Mass: 100.09 g/mo
  • Also known as: Aragonite, Calcite, Limestone, Marble

Preparation:

CaO + H₂O → Ca(OH)₂ Ca(OH)₂ + CO₂ → CaCO₃↓ + H₂O

PropertyDescription
Color & StateWhitish or milky crystalline powder
Odour & TasteOdourless; bitter taste
SolubilityPractically insoluble in water and ethanol
  • Preparation: Tablets, syrup, capsule, pills, toothpaste, tooth powder, oral drops.
  • Brand names: Shelcal, Calvitan, Acidocid SF, Calcimax P.
  • Storage: Well-closed, airtight container; away from light and moisture

Uses:

  • Acts as antacid — neutralises excess gastric acid; prevents indigestion and heartburn
  • Vital for growth and maturation of muscles, bones, teeth, and organs
  • Used in water treatment — forms complexes with harmful metals